四异丙基锡 ,Tetra-i-propyltin ,≥99%

产品编号:Bellancom-B280635| CAS NO:2949-42-0| 分子式:C12H28Sn| 分子量:291.0607

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货号 包装 价格 库存与货期 购买量 操作
Bellancom-B280635
5380.00 杭州 北京(现货)
Bellancom-B280635
1334.00 杭州 北京(现货)

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英文名称Tetra-i-propyltin
CAS编号2949-42-0
产品沸点89ºC (4 torr)
产品密度1.124 g/cm3
产品闪点>38ºC
精确质量292.12100
LogP5.07520
蒸气压0.0428mmHg at 25°C
折射率1.4851
稳定性

遵照规定使用和储存则不会分解。

储存条件

密闭于阴凉干燥环境中

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风险声明 (欧洲) R36/37/38
安全声明 (欧洲) 26-36/37/39
危险品运输编码 UN2788
包装等级 II
危险类别 6.1
海关编码 2931900090

Section 1: Product Identification
Chemical Name:Tetra-i-propyltin, min. 98%
CAS Registry Number:2949-42-0
Formula:Sn(C3H7)4
EINECS Number:220-969-5
Chemical Family:organotin compound
Synonym:Tetrakis(i-methylethyl)stannane

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound2949-42-0100%0.1mg/m30.1mg/m3

Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. Organo tin compounds may act as delayed poisons, causing
Emergency Overview:
headache, psycho-neurologic disturbances, vision impairment; skin burns, liver and kidney damage.
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes
Eye Contact:Causes severe irritation of the eyes.
Causes slight to mild irritation of the skin. Prolonged contact may dry the skin and lead to rashes or more
Skin Contact:
severe irritation.
Irritating to the nose, mucous membranes and respiratory tract. High doses may cause long term neurological
Inhalation:
damage.
Delayed and permanent psycho-neurologic disturbances; impairment of vision, unsteadiness, nausea and
Ingestion:
vomiting.
Irritating to skin, eyes and mucous membranes. Ingestion of certain organotin compounds may cause delayed
Acute Health Affects:
poisoning (4 days) with cerebral edema causing damage to the central nervous system.
Repeated exposure to certain organic tin compounds may cause problems with vision, skin, respiratory
Chronic Health Affects:
system, central nervous system, liver, kidneys, urinary tract, and blood .
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, foam or dry powder
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andcarbon monoxide, carbon dioxide, soot, organic fumes and tin compounds.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, ground limestone, sodium carbonate or other suitable
Spill and Leak Procedures:
noncombustible adsorbent and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry, well ventilated area away from heat and direct sunlight. Keep containers tightly sealed.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Work with this product in a well-ventilated area, preferably a fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Work with this product in a well-ventilated area, preferably a fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:colorless liq.
Molecular Weight:291.05
Melting Point:no data
Boiling Point:112-114°C /18 mm
Vapor Pressure:no data
Specific Gravity:no data
Odor:not determined
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:strong oxidizing agents and halogens
Decomposition Products:carbon monoxide, carbon dioxide, tin oxide, and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:Intravenous (mouse); LD50: 56 mg/kg.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to federal, state, and local regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

~23%

2949-42-0结构式

2949-42-0

文献:Sasin et al. Journal of Organic Chemistry, 1958 , vol. 23, p. 1366

~0%

2949-42-0结构式

2949-42-0

详细
文献:Olszowy, Henry A.; Kitching, William Organometallics, 1984 , vol. 3, p. 1670 - 1675

~55%

详细
文献:Organometallics, , vol. 1, p. 1244 - 1246

~%

2949-42-0结构式

2949-42-0

文献:Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 249, p. 1359

~%

2949-42-0结构式

2949-42-0

文献:Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 240, p. 1732

~%

2949-42-0结构式

2949-42-0

文献:Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 384, p. 89 - 96 Sn: Org.Verb.1, 1.1.1.4.1, page 90 - 91

~%

2949-42-0结构式

2949-42-0

文献:Bulletin de la Societe Chimique de France, , vol. 22, p. 12 Sn: Org.Verb.1, 1.1.1.4.1, page 90 - 91

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