α-(N,N-二甲基氨基)乙基二茂铁 ,alpha-(N,N-Dimethylamino)ethylferrocene ,99%
产品编号:Bellancom-B281496| CAS NO:31904-34-4| 分子式:C14H17FeN| 分子量:255.1365
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英文名称 | alpha-(N,N-Dimethylamino)ethylferrocene |
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CAS编号 | 31904-34-4 |
产品沸点 | 120-121°C 0,7mm |
产品密度 | 1.222 |
产品闪点 | >110°C |
精确质量 | 257.08700 |
PSA | 3.24000 |
LogP | 2.36080 |
外观性状 | liquid | orange |
折射率 | n20/D 1.587 |
溶解性 | Not miscible or difficult to mix in water. |
稳定性 | 如果遵照规格使用和储存则不会分解,未有已知危险反应 |
储存条件 | 保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置 |
相关文档
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危害码 (欧洲) | Xn: Harmful; |
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风险声明 (欧洲) | R36/38 |
安全声明 (欧洲) | S26-S36 |
Section 1: Product Identification Chemical Name:alpha-(N,N-Dimethylamino)ethylferrocene, 98% CAS Registry Number:31904-34-4 Formula:(C5H5)Fe(C5H4CH(CH3)N(CH3)2) EINECS Number:None Chemical Family:metallocene Synonym:bis-alpha-(N,N-Dimethylamino)ethylcyclopentadienyl iron
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound31904-34-4100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Ingestion, inhalation of dust. Eyes and skin. Eye Contact:Causes moderate irritation of the eyes. Skin Contact:Causes slight to moderate irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No specific information on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards Chronic Health Affects: may be present. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry area away from heat and direct sunlight. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:orange liq. Molecular Weight:257.16 Melting Point:no data Boiling Point:110°C/0.45mm Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:Oxidizing agents and halogens Decomposition Products:carbon dioxide, carbon monoxide, nitrogen oxides, organic fumes, and iron oxide SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:None SECTION 16 - ADDITIONAL INFORMATION N/A |
~88% ![]() 31904-34-4 |
文献:Gokel, G.; Hoffmann, P.; Klusacek, H.; Marquarding, D.; Ruch, E.; Ugi, I. Angewandte Chemie, International Edition in English, 1970 , vol. 9, p. 64 - 65 Full Text Show Details Gokel, G.; Hoffmann, P.; Klusacek, H.; Marquarding, D.; Ruch, E.; Ugi, I. Angewandte Chemie, 1970 , vol. 82, p. 77 - 78 Full Text Show Details Gmelin Handbook: Fe: Org.Verb.A4, 5.1.4.1.3.3, page 52 - 55 |
~53% ![]() 31904-34-4 |
文献:Gmelin Handbook: Fe: Org.Verb.A4, 5.1.4.1.3.3, page 52 - 55 |
~% ![]() 31904-34-4 |
文献:Butler, Ian R.; Cullen, William R. Canadian Journal of Chemistry, 1983 , vol. 61, p. 2354 - 2358 |
~60% ![]() 31904-34-4 |
文献:Gmelin Handbook: Fe: Org.Verb.A4, 5.1.4.1.3.3, page 52 - 55 |
~% ![]() 31904-34-4 |
文献:Angewandte Chemie, International Edition in English, , vol. 9, p. 64 - 65 Angewandte Chemie, , vol. 82, p. 77 - 78 Fe: Org.Verb.A4, 5.1.4.1.1.2, page 10 - 22 |
~% ![]() 31904-34-4 |
文献:Dixneuf, P.; Dabard, R. Bulletin de la Societe Chimique de France, 1972 , p. 2838 - 2847 Full Text Show Details Gmelin Handbook: Fe: Org.Verb.A4, 5.1.4.1.3.3, page 52 - 55 |
~% ![]() 31904-34-4 |
文献:Bulletin de la Societe Chimique de France, , p. 2838 - 2847 Fe: Org.Verb.A4, 5.1.4.1.3.3, page 52 - 55 |
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