(S)-(+)-1-(氨基苯甲酰基)-2-奈酚 ,(S)-(+)-1-(alpha-AMinobenzyl)-2-naphthol ,98%
产品编号:Bellancom-B291176| CAS NO:219897-38-8| 分子式:C17H15NO| 分子量:249.30700
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英文名称 | (S)-(+)-1-(alpha-AMinobenzyl)-2-naphthol |
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CAS编号 | 219897-38-8 |
产品熔点 | 133-137ºC |
产品沸点 | 451.1ºC at 760mmHg |
产品闪点 | 226.6ºC |
精确质量 | 249.11500 |
PSA | 46.25000 |
LogP | 4.29380 |
蒸气压 | 9.38E-09mmHg at 25°C |
稳定性 | 1.遵照规定使用和储存则不会分解。 2.该试剂在游离胺状态下不稳定,会自动分解。一般以盐酸盐或者酒石酸盐的形式储存和使用。 |
储存条件 | 密闭于4 ºC阴凉干燥环境中 |
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危害码 (欧洲) | Xi: Irritant; |
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风险声明 (欧洲) | R36/37/38 |
安全声明 (欧洲) | 37/39-36 |
海关编码 | 2922299090 |
Synonym:(S)-Betti bas Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Moisture sensitive. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Keep refrigerated. (Store below 4C/39F.) Store in a tightly closed container. Store in a dry area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 219897-38-8: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: white to off-white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 133 - 137 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: 259 deg C Solubility in water: Insoluble. Specific Gravity/Density: Molecular Formula: C17H15NO Molecular Weight: 249.31 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, strong reducing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 219897-38-8 unlisted. LD50/LC50: Not available. Carcinogenicity: (S)-(+)-1-(alpha-Aminobenzyl)-2-naphthol - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: IMO Shipping Name: Not regulated. Hazard Class: UN Number: Packing Group: RID/ADR Shipping Name: Not regulated. Hazard Class: UN Number: Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 36 Wear suitable protective clothing. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 219897-38-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 219897-38-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 219897-38-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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文献:Periasamy, Mariappan; Anwar, Shaik; Reddy, Meda Narsi Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2009 , vol. 48, # 9 p. 1261 - 1273 |
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文献:Synthesis (Germany), , vol. 45, # 7 art. no. SS-2012-H0910-OP, p. 899 - 902 |
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文献:Synthesis (Germany), , vol. 45, # 7 art. no. SS-2012-H0910-OP, p. 899 - 902 |
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