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醋酸(III)水合物 ,Praseodymium acetate ,99.9%-Pr(REO)

产品编号:Bellancom-B293764| CAS NO:6192-12-7| 分子式:C22H25N3O2| 分子量:363.4528

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货号 包装 价格 库存与货期 购买量 操作
Bellancom-B293764
348.00 杭州 北京(现货)
Bellancom-B293764
4032.00 杭州 北京(现货)
Bellancom-B293764
1014.00 杭州 北京(现货)
Bellancom-B293764
1110.00 杭州 北京(现货)

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产品名称 醋酸(III)水合物
英文名称Praseodymium acetate
CAS编号6192-12-7
产品沸点536.2ºC at 760 mmHg
产品密度1.2g/cm3
产品闪点278.1ºC
精确质量371.979218
PSA78.90000
外观性状绿色固体
折射率1.618
稳定性

常温常压下稳定,绿色水晶颗粒。

溶于水,难溶于乙醇,不溶于吡啶。加热至270℃以上分解。加热至790℃时,生成氧化镨(Ⅲ,Ⅳ)。(Pr6O11)。

与DMF作用,得到Pr(CH3COO)3·DMF,熔点151~155℃,真空加热至210℃,可脱去DMF。与1,10菲咯啉作用[157],得到绿色结晶,加热至270~300℃分解。与硫脲作用,得到熔点为197~198℃绿色结晶,溶于水。与2,2′-联吡啶作用,得到的络合物为绿色晶体,加热至250~260℃分解。

储存条件

避光,阴凉干燥处,密封保存

相关文档

化学品安全说明书(MSDS)

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风险声明 (欧洲) R36/37/38
安全声明 (欧洲) S26-S36-S37-S39

Section 1: Product Identification
Chemical Name:Praseodymium (III) acetate hydrate (99.9%-Pr) (REO)
CAS Registry Number:6192-12-7
Formula:Pr(OOCCH3)3.XH2O
EINECS Number:none
Chemical Family:metal acetate salt
Synonym:Acetic acid, praseodymium(+3) salt, hydrate

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound6192-12-7100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Store in a tightly sealed container in a dry place. If container is left open, salt may adsorb moisture from the
Handling and Storage:
atmosphere.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:green xtl.
Molecular Weight:318.04
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:very soluble

SECTION 10: Stability and Reactivity
Stability:hygroscopic solid
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:contact with moisture
Incompatibility:Oxidizing agents and active metals
Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

~%

6192-12-7结构式

6192-12-7

文献:Egypt. J. Chem., , vol. 26, p. 125 - 132 Sc: MVol.D4, 1.4.10, page 52 - 53

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