茚,Indene,99%
产品编号:西域试剂-WR381793| CAS NO:95-13-6| MDL NO:MFCD00003777| 分子式:C9H8| 分子量:116.16
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产品名称 | 茚 |
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英文名称 | Indene |
CAS编号 | 95-13-6 |
产品熔点 | −5-−3 °C(lit.) |
产品沸点 | 181.6±0.0 °C at 760 mmHg |
产品密度 | 1.0±0.1 g/cm3 |
产品闪点 | 58.9±0.0 °C |
精确质量 | 116.062599 |
LogP | 2.91 |
外观性状 | 淡黄色至橙色液体 |
蒸气压 | 1.2±0.2 mmHg at 25°C |
折射率 | 1.596 |
溶解性 | INSOLUBLE |
稳定性 | 1.本品可燃,遇明火高温有燃烧危险。在空气中易氧化,暴露在空气和日光中能形成聚合物。避免与氧化物、光接触。 2.大鼠可耐受反复六次吸入3.8~4.2mg/L本品而无可见中毒症状。工作场所空气中最大容许浓度为240mg/m3。 3. 存在于烟气中。 |
储存条件 | 1.储存于阴凉、通风的库房。远离火种、热源。防止阳光直射。远离火源,防静电。包装密封。应与氧化剂分开存放,切忌混储。配备相应品种和 数量的消防器材。储区应备有合适的材料收容泄漏物。 2.本品可燃,遇明火,高热,有发生燃烧危险,应贮存阴凉,通风良好仓库内,远离热源,火种,与氧化剂分开存放,轻装轻卸,保持包装完整,不宜久存,防止变质。
3. 贮藏过程中能聚合和氧化。 |
相关文档
化学品安全说明书(MSDS)
下载MSDS质检证书(COA)
相关产品
符号 |
![]() ![]() GHS02, GHS08 |
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信号词 | Danger |
危害声明 | H226-H304 |
警示性声明 | P301 + P310-P331 |
个人防护装备 | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
危害码 (欧洲) | Xn:Harmful; |
风险声明 (欧洲) | R10;R65 |
安全声明 (欧洲) | S23-S24/25-S62 |
危险品运输编码 | UN 3295 3/PG 3 |
WGK德国 | 1 |
RTECS号 | NK8225000 |
包装等级 | III |
危险类别 | 3 |
Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Air sensitive. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Ingestion: May cause liver and kidney damage. May cause digestive tract disturbances. Inhalation: May cause respiratory tract irritation. Chronic: May cause liver and kidney damage. Repeated exposure may cause sensitization dermatitis. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Combustible liquid. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated. Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep under a nitrogen blanket. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.) Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits CAS# 95-13-6: United Kingdom, WEL - TWA: 10 ppm TWA; 48 mg/m3 TWA United Kingdom, WEL - STEL: 15 ppm STEL; 72 mg/m3 STEL Belgium - TWA: 10 ppm VLE; 49 mg/m3 VLE France - VME: 10 ppm VME; 45 mg/m3 VME Germany: 45 mg/m3 TWA Malaysia: 10 ppm TWA; 48 mg/m3 TWA Netherlands: 10 ppm MAC; 45 mg/m3 MAC Spain: 10 ppm VLA-ED; 48 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: clear, colorless Odor: None reported. pH: Not available. Vapor Pressure: 1.7 hPa @ 20 C Viscosity: Not available. Boiling Point: 181 deg C @ 760.00mm Hg Freezing/Melting Point: -1.8 deg C Autoignition Temperature: Not available. Flash Point: 78 deg C ( 172.40 deg F) Explosion Limits, lower: N/A Explosion Limits, upper: N/A Decomposition Temperature: Solubility in water: insoluble Specific Gravity/Density: .9920g/cm3 Molecular Formula: C9H8 Molecular Weight: 116.16 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Oxidizes when exposed to air. Stable. However may polymerize explosively if heated to the melting point. Conditions to Avoid: Incompatible materials, ignition sources, exposure to air, excess heat, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: May occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 95-13-6: NK8225000 LD50/LC50: CAS# 95-13-6: Inhalation, rat: LC50 = 14 gm/m3; Inhalation, rat: LC50 = 14000 mg/m3/4H. Carcinogenicity: Indene - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: FLAMMABLE LIQUID, N.O.S.* Hazard Class: 3 UN Number: 1993 Packing Group: III IMO Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3.3 UN Number: 1993 Packing Group: III RID/ADR Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3 UN Number: 1993 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 95-13-6: No information available. Canada CAS# 95-13-6 is listed on Canada's DSL List. CAS# 95-13-6 is listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 95-13-6 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
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